Hi sayersc, welcome to Hydrogenaudio!
Thanks a lot for your effort. I loaded your sample (beginning of Santana - Supernatural (05) Smooth) - with CoolEditPro.
1st I checked the 'silence' in the beginning of the track - there's a short part with
24bit LSB dither/noise = +/- 1 amplitude.
But on the other hand there's no content > 20kHz in spectral view / frequency analysis besides a few clicks that are obviously (ripping?) errors.
I own the CD version, unfortunately I can't find the CD right now, but the Musepack insane version is on my HDD, so I compared. Here's the frequency responses of DVD-A vs. CD version (same passage, volume adjusted, DVD-A version resampled to 44.1kHz, only left channel):

!!! The red graph is CD->MPC version, the green one is DVD-A !!!
So obviously the 'DVD-A' version has a 8-16kHz lowpass!

Besides this, I noticed this: The CD version is recorded too loud as many recent pop CDs (replaygain values -7.5/-7.8dB), on basedrum hits there's heavy clipping (nearly horizontal line with ~ full scale sample values > 100 samples in a row). The 'DVD-A' version is amplified by ~ -5dB compared to the CD version but has almost the same horizontal lines ("almost", because the lines are somewhat smoothed, probably because of lowpass).
Examples:

CD->MPC version

'DVD-A' version
Conclusions:
- The 'DVD-A' version seems to be 24bit resolution because of the LSB noise. This noise might have occured during 'ripping', though (IIRC there were some reports that some newer Windows versions do some LSB changes on directsound/waveout playback - this could also explain the LSB noise during silence).
- No audible content > 20kHz and the lowpass are strange, so either
- this 'DVD-A' contains an upsampled CD 'rip' with lowered volume that has been lowpassed to make it sound more vinyl-like
or - your DVD-A contains the same songs as DVD-V version (= video with AC3 or DTS audio stream) for compatibility reasons and you've ripped that one.
As the lowpass is easily audible you could try to check this (if you have a standalone DVD-A player) - compare playback through WinDVD + souncard with standalone DVD-A player playback (use same headphones /amp+speakers).
Cheers tigre