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Are they like (I have to use CDex for an example) where you can choose VBR, and then choose the quality of the VBR? As in 0, which is highest, and 9 which is lowest, along with several other variables? Or am I even farther off the track?
MPC is always VBR. AFAIK there is no way to make it CBR. With MPC you choose a quality level and the encoder does the rest. For some reference settings go
here. MP3 can be either VBR or CBR, but in a similar fashion to MPC, you select a quality level, and the encoder pops out a great MP3. For MP3 reference settings go
here.
As was said earlier, if you're looking for transparency, standard for MPC and --alt-preset standard for MP3 should be your best choices.
Both codecs are command line, but there are plenty of frontends around. When ripping/encoding, I set up EAC to do it all in one go. If you're converting from WAV or to WAV, I like
Speek's frontends. The top two progs will be for you, depending on which format you choose. And try out the multi frontend (at the bottom of the page) too.