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It would be like the equivalent in terms of quality of a 640 kbps mp3 stereo file right?
Nope! 
With
Joint Stereo the MP3 encoder knows that you have redundant information and this is all taken into account. You'll get essentially the same results with encoding your dual mono file to joint stereo as with encoding mono-to-mono. (I'd actually prefer the true-mono MP3 because it will be properly identified as mono, whereas the joint stereo file will show-up as stereo.)
When you encode a true-stereo file with joint stereo, the redundant information is also taken into account. This means that
you don't need twice the bitrate for the quality a stereo file to equal that of a mono file. (If you had a special case such as an English language soundtrack on the left channel and a French language soundtrack on the right, then there would be no redundant information and joint stereo would not be an advantage.)
And at these high bitrates,
there would be no audio quality difference between 320 and 640kbps anyway. Both would sound identical, and with most files they would both sound identical to the uncompressed original...